Name:
Ethyl Alcohol Denatured (A407)
Synonym:
Ethanol denatured; grain alcohol denatured; ethyl hydroxide denatured; ethyl hydrate denatured; algarin denature
CAS:
64-17-5
Section 1 - Chemical Product
MSDS Name:Ethyl Alcohol Denatured (A407)
Synonym:Ethanol denatured; grain alcohol denatured; ethyl hydroxide denatured; ethyl hydrate denatured; algarin denature
Synonym:Ethanol denatured; grain alcohol denatured; ethyl hydroxide denatured; ethyl hydrate denatured; algarin denature
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 64-17-5 | Ethyl Alcohol | 85.4-92. | 200-578-6 |
| Hazard Symbols: F Risk Phrases: |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable.Flammable liquid.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. May cause painful sensitization to light. Vapors may cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May be absorbed through the skin.
Ingestion:
May cause systemic toxicity with acidosis. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. May cause effects similar to those described for ingestion. May cause drowsiness, unconsciousness, and central nervous system depression.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. Prolonged or repeated skin contact may cause defatting and dermatitis. Prolonged or repeated exposure may cause adverse reproductive effects. May cause fetal effects.
Highly flammable.Flammable liquid.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. May cause painful sensitization to light. Vapors may cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May be absorbed through the skin.
Ingestion:
May cause systemic toxicity with acidosis. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. May cause effects similar to those described for ingestion. May cause drowsiness, unconsciousness, and central nervous system depression.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. Prolonged or repeated skin contact may cause defatting and dermatitis. Prolonged or repeated exposure may cause adverse reproductive effects. May cause fetal effects.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. A vapor suppressing foam may be used to reduce vapors.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. A vapor suppressing foam may be used to reduce vapors.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear, colorless
Odor: aromatic odor
pH: No data
Vapor Pressure: 25 mm Hg
Viscosity: Not available.
Boiling Point: 173.3 deg F
Freezing/Melting Point: -90 deg C
Autoignition Temperature: 685 deg F ( 362.78 deg C)
Flash Point: 13 deg C ( 55.40 deg F)
Explosion Limits, lower: 3.3 (ethanol)
Explosion Limits, upper: 19 (ethanol)
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 0.7905
Molecular Formula: Mixture.
Molecular Weight: Not available.
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable. This material may be sensitive to peroxide formation.
Conditions to Avoid:
This material may be sensitive to peroxide formation., incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Isopropanol is susceptible to autoxidation and therefore should be classified as peroxidizable., acids (mineral, non-oxidizing, e.g.
hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g. methyl isocyanate), metals (alkali and alkaline, e.g. cesium, potassium, sodium), nitrides (e.g. potassium nitride, sodium nitride), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents (strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide, potassium nitrate), reducing agents (strong, e.g. aluminum carbide, chlorosilane, hydrogen phosphide, lithium hydride), water reactive substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium carbide, ethyl dichlorosilane).
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable. This material may be sensitive to peroxide formation.
Conditions to Avoid:
This material may be sensitive to peroxide formation., incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Isopropanol is susceptible to autoxidation and therefore should be classified as peroxidizable., acids (mineral, non-oxidizing, e.g.
hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g. methyl isocyanate), metals (alkali and alkaline, e.g. cesium, potassium, sodium), nitrides (e.g. potassium nitride, sodium nitride), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents (strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide, potassium nitrate), reducing agents (strong, e.g. aluminum carbide, chlorosilane, hydrogen phosphide, lithium hydride), water reactive substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium carbide, ethyl dichlorosilane).
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 67-63-0: NT8050000 CAS# 67-64-1: AL3150000 CAS# 71-43-2: CY1400000 CAS# 75-07-0: AB1925000 CAS# 108-10-1: SA9275000 CAS# 108-88-3: XS5250000 CAS# 141-78-6: AH5425000 CAS# 7732-18-5: ZC0110000 CAS# 64742-89-8 unlisted.
CAS# 308082-09-9 unlisted.
LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5628 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 67-63-0: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 10 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 500 mg Mild; Inhalation, rat: LC50 = 16000 ppm/8H; Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit: LD50 = 12800 mg/kg.
CAS# 67-64-1: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 44 gm/m3/4H; Inhalation, rat: LC50 = 50100 mg/m3/8H; Oral, mouse: LD50 = 3 gm/kg; Oral, rabbit: LD50 = 5340 mg/kg; Oral, rat: LD50 = 5800 mg/kg.
CAS# 71-43-2: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test, rabbit, eye: 88 mg Moderate; Draize test, rabbit, eye: 2 mg/24H Severe; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 9980 ppm; Inhalation, rat: LC50 = 10000 ppm/7H; Oral, mouse: LD50 = 4700 mg/kg; Oral, rat: LD50 = 930 mg/kg; Skin, rabbit: LD50 = >9400 uL/kg.
CAS# 75-07-0: Draize test, rabbit, eye: 40 mg Severe; Inhalation, mouse: LC50 = 23 gm/m3/4H; Inhalation, rat: LC50 = 13300 ppm/4H; Oral, mouse: LD50 = 900 mg/kg; Oral, rat: LD50 = 661 mg/kg; Skin, rabbit: LD50 = 3540 mg/kg.
CAS# 108-10-1.
CAS# 108-88-3.
CAS# 141-78-6: Inhalation, mouse: LC50 = 45 gm/m3/2H; Inhalation, rat: LC50 = 200 gm/m3; Oral, mouse: LD50 = 4100 mg/kg; Oral, rabbit: LD50 = 4935 mg/kg; Oral, rat: LD50 = 5620 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 7732-18-5.
CAS# 64742-89-8.
CAS# 308082-09-9.
Carcinogenicity:
Ethyl Alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Isopropyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Acetone - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Benzene - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Acetaldehyde - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl isobutyl ketone - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Toluene - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Ethyl acetate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Water - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Solvent naphtha (petroleum), light aliphatic - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Gasoline, aviation - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 67-63-0: NT8050000 CAS# 67-64-1: AL3150000 CAS# 71-43-2: CY1400000 CAS# 75-07-0: AB1925000 CAS# 108-10-1: SA9275000 CAS# 108-88-3: XS5250000 CAS# 141-78-6: AH5425000 CAS# 7732-18-5: ZC0110000 CAS# 64742-89-8 unlisted.
CAS# 308082-09-9 unlisted.
LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5628 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 67-63-0: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 10 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 500 mg Mild; Inhalation, rat: LC50 = 16000 ppm/8H; Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit: LD50 = 12800 mg/kg.
CAS# 67-64-1: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 44 gm/m3/4H; Inhalation, rat: LC50 = 50100 mg/m3/8H; Oral, mouse: LD50 = 3 gm/kg; Oral, rabbit: LD50 = 5340 mg/kg; Oral, rat: LD50 = 5800 mg/kg.
CAS# 71-43-2: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test, rabbit, eye: 88 mg Moderate; Draize test, rabbit, eye: 2 mg/24H Severe; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 9980 ppm; Inhalation, rat: LC50 = 10000 ppm/7H; Oral, mouse: LD50 = 4700 mg/kg; Oral, rat: LD50 = 930 mg/kg; Skin, rabbit: LD50 = >9400 uL/kg.
CAS# 75-07-0: Draize test, rabbit, eye: 40 mg Severe; Inhalation, mouse: LC50 = 23 gm/m3/4H; Inhalation, rat: LC50 = 13300 ppm/4H; Oral, mouse: LD50 = 900 mg/kg; Oral, rat: LD50 = 661 mg/kg; Skin, rabbit: LD50 = 3540 mg/kg.
CAS# 108-10-1.
CAS# 108-88-3.
CAS# 141-78-6: Inhalation, mouse: LC50 = 45 gm/m3/2H; Inhalation, rat: LC50 = 200 gm/m3; Oral, mouse: LD50 = 4100 mg/kg; Oral, rabbit: LD50 = 4935 mg/kg; Oral, rat: LD50 = 5620 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 7732-18-5.
CAS# 64742-89-8.
CAS# 308082-09-9.
Carcinogenicity:
Ethyl Alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Isopropyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Acetone - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Benzene - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Acetaldehyde - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl isobutyl ketone - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Toluene - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Ethyl acetate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Water - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Solvent naphtha (petroleum), light aliphatic - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Gasoline, aviation - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Rainbow trout: LC50 = 12900-15300 mg/L; 96 Hr; Flow-through @ 24-24.3CFish: Rainbow trout: LC50 = 11200 mg/L; 24 Hr; Fingerling (Unspecified)Bacteria: Phytobacterium phosphoreum: EC50 = 34900 mg/L; 5-30 min; Microtox test250 ppm/6hr/goldfish/lethal/fresh water
Fish: Rainbow trout: LC50 = 12900-15300 mg/L; 96 Hr; Flow-through @ 24-24.3CFish: Rainbow trout: LC50 = 11200 mg/L; 24 Hr; Fingerling (Unspecified)Bacteria: Phytobacterium phosphoreum: EC50 = 34900 mg/L; 5-30 min; Microtox test250 ppm/6hr/goldfish/lethal/fresh water
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 2 Keep out of reach of children.
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 67-56-1: 1
CAS# 67-63-0: 1
CAS# 67-64-1: 0
CAS# 71-43-2: 3
CAS# 75-07-0: 1
CAS# 108-10-1: 1
CAS# 108-88-3: 2
CAS# 141-78-6: 1
CAS# 7732-18-5: No information available.
CAS# 64742-89-8: No information available.
CAS# 308082-09-9: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 64-17-5 is not listed on Canadas Ingredient Disclosure List.
CAS# 67-56-1 is not listed on Canadas Ingredient Disclosure List.
CAS# 67-63-0 is not listed on Canadas Ingredient Disclosure List.
CAS# 67-64-1 is not listed on Canadas Ingredient Disclosure List.
CAS# 71-43-2 is not listed on Canadas Ingredient Disclosure List.
CAS# 75-07-0 is not listed on Canadas Ingredient Disclosure List.
CAS# 108-10-1 is not listed on Canadas Ingredient Disclosure List.
CAS# 108-88-3 is not listed on Canadas Ingredient Disclosure List.
CAS# 141-78-6 is not listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
CAS# 64742-89-8 is not listed on Canadas Ingredient Disclosure List.
CAS# 308082-09-9 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 64-17-5: OEL-AUSTRALIA:TWA 1000 ppm (1900 mg/m3)
OEL-BELGIUM:TWA 1000 ppm (1880 mg/m3)
OEL-CZECHOSLOVAKIA:TWA 1000 mg/m3;STEL 5000 mg/m3
OEL-DENMARK:TWA 1000 ppm (1900 mg/m3)
OEL-FINLAND:TWA 1000 ppm (1900 mg/m3);STEL 1250 ppm (2400 mg/m3)
OEL-FRANCE:TWA 1000 ppm (1900 mg/m3);STEL 5000 pp
OEL-GERMANY:TWA 1000 ppm (1900 mg/m3)
OEL-HUNGARY:TWA 1000 mg/m3;STEL 3000 mg/m3
OEL-THE NETHERLANDS:TWA 1000 ppm (1900 mg/m3)
OEL-THE PHILIPPINES:TWA 1000 ppm (1900 mg/m3)
OEL-POLAND:TWA 1000 mg/m3
OEL-RUSSIA:STEL 1000 mg/m3
OEL-SWEDEN:TWA 1000 ppm (1900 mg/m3)
OEL-SWITZERLAND:TWA 1000 ppm (1900 mg/m3)
OEL-THAILAND:TWA 1000 ppm (1900 mg/m3)
OEL-TURKEY:TWA 1000 ppm (1900 mg/m3)
OEL-UNITED KINGDOM:TWA 1000 ppm (1900 mg/m3) JAN9
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 67-56-1: OEL-ARAB Republic of Egypt:TWA 200 ppm (260 mg/m3);Skin
CAS# 67-63-0: OEL-AUSTRALIA:TWA 400 ppm (980 mg/m3);STEL 500 ppm (1225
mg/m3)
OEL-BELGIUM:TWA 400 ppm (985 mg/m3);STEL 500 ppm (1230 mg/m3)
OEL-DENMARK:TWA 200 ppm (490 mg/m3);Skin
OEL-FRANCE:STEL 400 ppm (980 mg/m3)
OEL-GERMANY:TWA 400 ppm (980 mg/m3)
OEL-JAPAN:STEL 400 ppm (980 mg/m3)
OEL-THE NETHERLANDS:TWA 400 ppm (980 mg/m3);Skin
OEL-THE PHILIPPINES:TWA 400 ppm (980 mg/m3)
OEL-RUSSIA:STEL 400 ppm (10 mg/m3)
OEL-SWEDEN:TWA 150 ppm (350 mg/m3);STEL 250 ppm (600 mg/m3)
OEL-SWITZERLAND:TWA 400 ppm (980 mg/m3);STEL 800 ppm
OEL-TURKEY:TWA 200 ppm (500 mg/m3)
OEL-UNITED KINGDOM:TWA 400 ppm (980 mg/m3);STEL 500 ppm;Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 67-64-1: OEL-AUSTRALIA:TWA 500 ppm (1185 mg/m3);STEL 1000 ppm
OEL-AUSTRIA:TWA 750 ppm (1780 mg/m3)
OEL-BELGIUM:TWA 750 ppm (1780 mg/m3);STEL 1000 pp
OEL-CZECHOSLOVAKIA:TWA 800 mg/m3;STEL 4000 mg/m3
OEL-DENMARK:TWA 250 ppm (600 mg/m3)
OEL-FINLAND:TWA 500 ppm (1200 mg/m3);STEL 625 ppm (1500 mg/m3)
OEL-FRANCE:TWA 750 ppm (1800 mg/m3)
OEL-GERMANY:TWA 1000 ppm (2400 mg/m3)
OEL-HUNGARY:TWA 600 mg/m3;STEL 1200 mg/m3
OEL-INDIA:TWA 750 ppm (1780 mg/m3);STEL 1000 ppm (2375 mg/m3)
OEL-JAPAN:TWA 200 ppm (470 mg/m3)
OEL-THE NETHERLANDS:TWA 750 ppm (1780 mg/m3) JAN9
OEL-THE PHILIPPINES:TWA 1000 ppm (2400 mg/m3)
OEL-POLAND:TWA 200 mg/m3
OEL-RUSSIA:TWA 200 ppm;STEL 200 mg/m3
OEL-SWEDEN:TWA 250 ppm (600 mg/m3);STEL 500 ppm (1200 mg/m3)
OEL-SWITZERLAND:TWA 750 ppm (1780 mg/m3)
OEL-TURKEY:TWA 1000 ppm (2400 mg/m3)
OEL-UNITED KINGDOM:TWA 750 ppm (1810 mg/m3);STEL 1250 ppm
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV CAS# 71-43-2: OEL-AUSTRALIA:TWA 5 ppm (16 mg/m3);Carcinogen
OEL-BELGIUM:TWA 10 ppm (32 mg/m3);Carcinogen JAN9
OEL-CZECHOSLOVAKIA:TWA 10 mg/m3;STEL 20 mg/m3
OEL-DENMARK:TWA 5 ppm (16 mg/m3);Skin;Carcinogen
OEL-FINLAND:TWA 5 ppm (15 mg/m3);STEL 10 ppm (30 mg/m3);Skin;CAR
OEL-FRANCE:TWA 5 ppm (16 mg/m3);Carcinogen
OEL-GERMANY;Skin;Carcinogen
OEL-HUNGARY:STEL 5 mg/m3;Skin;Carcinogen
OEL-INDIA:TWA 10 ppm (30 mg/m3);Carcinogen
OEL-JAPAN:TWA 10 ppm (32 mg/m3);STEL 25 ppm (80 mg/m3);CAR
OEL-THE NETHERLANDS:TWA 10 ppm (30 mg/m3);Skin
OEL-THE PHILIPPINES:TWA 25 ppm (80 mg/m3);Skin
OEL-POLAND:TWA 30 mg/m3;Skin
OEL-RUSSIA:TWA 10 ppm (5 mg/m3);STEL 25 ppm (15 mg/m3);Skin;CAR
OEL-SWEDEN:TWA 1 ppm (3 mg/m3);STEL 5 ppm (16 mg/m3);Skin;CAR
OEL-SWITZERLAND:TWA 5 ppm (16 mg/m3);Skin;Carcinogen
OEL-THAILAND:TWA 10 ppm (30 mg/m3);STEL 25 ppm (7 mg/m3)
OEL-TURKEY:TWA 20 ppm (64 mg/m3);Skin
OEL-UNITED KINGDOM:TWA 10 ppm (30 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 75-07-0: OEL-ARAB Republic of Egypt:TWA 100 ppm (180 mg/m3)
OEL-AUSTRALIA:TWA 100 ppm (180 mg/m3);STEL 150 pp (270 mg/m3)
OEL-BELGIUM:TWA 100 ppm (180 mg/m3);STEL 150 ppm (270 mg/m3)
OEL-CZECHOSLOVAKIA:TWA 200 mg/m3;STEL 400 mg/m3;CAR
OEL-DENMARK:TWA 25 ppm (45 mg/m3)
OEL-FINLAND:TWA 50 ppm (90 mg/m3);STEL 75 ppm (13 mg/m3)
OEL-FRANCE:TWA 100 ppm (180 mg/m3)
OEL-GERMANY:TWA 50 ppm (90 mg/m3);Carcinogen JAN9
OEL-HUNGARY:STEL 25 mg/m3;Carcinogen
OEL-INDIA:TWA 100 ppm (180 mg/m3);STEL 150 ppm (270 mg/m3)
OEL-THE NETHERLANDS:TWA 100 ppm (180 mg/m3)
OEL-THE PHILIPPINES:TWA 200 ppm (360 mg/m3)
OEL-POLAND:TWA 5 mg/m3
OEL-RUSSIA:STEL 5 mg/m3;Skin
OEL-SWEDEN:TWA 25 ppm (45 mg/m3);STEL 50 ppm (90 mg/m3)
OEL-SWITZERLAND:TWA 50 ppm (90 mg/m3);STEL 100 pp (180 mg/m3)
OEL-TURKEY:TWA 200 ppm (360 mg/m3)
OEL-UNITED KINGDOM:TWA 100 ppm (180 mg/m3);STEL 150 ppm
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 108-10-1: Not available.
CAS# 108-88-3: OEL-AUSTRALIA:TWA 100 ppm (375 mg/m3);STEL 150 ppm (560
mg/m3)
OEL-BELGIUM:TWA 100 ppm (377 mg/m3);STEL 150 ppm (565 mg/m3)
OEL-CZECHOSLOVAKIA:TWA 200 mg/m3;STEL 1000 mg/m3
OEL-DENMARK:TWA 50 ppm (190 mg/m3);Skin
OEL-FINLAND:TWA 100 ppm (375 mg/m3);STEL 150 ppm;Skin
OEL-FRANCE:TWA 100 ppm (375 mg/m3);STEL 150 ppm (560 mg/m3)
OEL-GERMANY:TWA 100 ppm (380 mg/m3)
OEL-HUNGARY:TWA 100 mg/m3;STEL 300 mg/m3;Skin
OEL-JAPAN:TWA 100 ppm (380 mg/m3)
OEL-THE NETHERLANDS:TWA 100 ppm (375 mg/m3);Skin
OEL-THE PHILIPPINES:TWA 100 ppm (375 mg/m3)
OEL-POLAND:TWA 100 mg/m3
OEL-RUSSIA:TWA 100 ppm;STEL 50 mg/m3
OEL-SWEDEN:TWA 50 ppm (200 mg/m3);STEL 100 ppm (400 mg/m3);Skin
OEL-SWITZERLAND:TWA 100 ppm (380 mg/m3);STEL 500 ppm
OEL-THAILAND:TWA 200 ppm;STEL 300 ppm
OEL-TURKEY:TWA 200 ppm (750 mg/m3)
OEL-UNITED KINGDOM:TWA 100 ppm (375 mg/m3);STEL 150 ppm;Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 141-78-6: OEL-AUSTRALIA:TWA 400 ppm (1400 mg/m3)
OEL-BELGIUM:TWA 400 ppm (1440 mg/m3)
OEL-CZECHOSLOVAKIA:TWA 400 mg/m3;STEL 2000 mg/m3
OEL-DENMARK:TWA 300 ppm (1100 mg/m3)
OEL-FINLAND:TWA 300 ppm (1100 mg/m3);STEL 500 ppm (1800 mg/m3)
OEL-FRANCE:TWA 400 ppm (1400 mg/m3)
OEL-GERMANY:TWA 400 ppm (1400 mg/m3)
OEL-HUNGARY:TWA 400 mg/m3;STEL 1200 mg/m3
OEL-JAPAN:TWA 400 ppm (1400 mg/m3)
OEL-THE NETHERLANDS:TWA 400 ppm (1400 mg/m3) JAN9
OEL-THE PHILIPPINES:TWA 400 ppm (1400 mg/m3) JAN9
OEL-POLAND:TWA 200 ppm
OEL-RUSSIA:TWA 400 ppm;STEL 200 mg/m3
OEL-SWEDEN:TWA 150 ppm (500 mg/m3);STEL 300 ppm (1100 mg/m3)
OEL-SWITZERLAND:TWA 400 ppm (1400 mg/m3);STEL 800 ppm
OEL-TURKEY:TWA 400 ppm (1400 mg/m3)
OEL-UNITED KINGDOM:TWA 400 ppm (1400 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
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